Traoré, Bocar and Excoffier, Grégory and Fall, Alioune and Thiam, Ibrahima Elhadj and Sidibé, Mamadou and Diouf, Ousmane and Gaye, Mohamed (2023) Synthesis, Crystal Structure and Spectroscopic Study of (E)-2-methoxy-4-((1-phenylethylimino)methyl)phenol. Chemical Science International Journal, 32 (6). pp. 129-136. ISSN 2456-706X
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Abstract
A new unsymmetrical ligand (E)-2-methoxy-4-((1-phenylethylimino)methyl)phenol C16N17NO2 (I), was synthetized by one-step condensation reaction. The structure of this new compound was confirmed by elemental analysis, FT-IR, UV-Visible and 1H and 13C NMR spectroscopy techniques. The compound (I) crystallizes in the orthorhombic space group P212121 with the following unit cell parameters a = 11.7570 (6) Å, b = 10.0711 (6) Å, c = 23.4478(13) Å, V = 2776.4(3) Å3, Z = 4, R1 = 0.045 and wR2 = 0.125. The title compound crystallizes with two enantiomers (A and B) in the asymmetric unit which are both in E-stereoisomers. In the crystal structure of the racemic compound, the most noticeable difference between these two molecules is the dihedral angle values between the phenyl rings: 61.61 (1)° and 60.96(1)°.
Item Type: | Article |
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Subjects: | Euro Archives > Chemical Science |
Depositing User: | Managing Editor |
Date Deposited: | 02 Jan 2024 05:53 |
Last Modified: | 02 Jan 2024 05:53 |
URI: | http://publish7promo.com/id/eprint/4312 |