Rhodium-phosphite Catalysed Hydroformylation of Camphene and Other Terpenes

Pagar, Nitin S. and Deshpande, Raj M. (2021) Rhodium-phosphite Catalysed Hydroformylation of Camphene and Other Terpenes. In: Current Perspectives on Chemical Sciences Vol. 7. B P International, pp. 30-38. ISBN 978-93-90516-67-4

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Abstract

The hydroformylation of camphene and other terpenes has been studied with homogeneous Rh, Co, and Pt metal complexes. Rh(CO)2(acac)/P(OPh)3 catalyst system has been found to be very active with almost total selectivity to aldehyde products. The role of ligands, solvents, Rh:P ratio and reaction conditions on the activity and selectivity towards camphene hydroformylation have been assessed. Kinetics of hydroformylation of camphene was investigated in the presence of [Rh(CO)2(acac)]/ P(OPh)3 catalyst in a temperature range of 363–383K.

Item Type: Book Section
Subjects: Euro Archives > Chemical Science
Depositing User: Managing Editor
Date Deposited: 06 Dec 2023 03:29
Last Modified: 06 Dec 2023 03:29
URI: http://publish7promo.com/id/eprint/3903

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