Investigation of Mechanical Properties, Durability and Microstructure of Low-Clinker High-Performance Concretes Incorporating Ground Granulated Blast Furnace Slag, Siliceous Fly Ash and Silica Fume

The main assumption of eco-efficient High-Performance Concrete (HPC) design is the reduction of Portland cement clinker content without negatively affecting the composite’s mechanical and durability properties. In this paper, three low-clinker HPC mixtures incorporating slag cement (CEM III/B as per EN 197-1) and Supplementary Cementitious Materials (SCMs)—Ground Granulated Blast Furnace Slag (GGBFS), Siliceous Fly Ash (SFA) and Silica Fume (SF)—were designed. The maximum amount of Portland cement clinker from CEM III/B varied from 64 to 116 kg in 1 m3 of concrete mix. The compressive strength of HPC at 2, 7, 14, 28, 56, 90 days, and 2 years after casting, as well as the modulus of elasticity on 2-year-old specimens, was tested. The depth of water penetration under pressure and internal frost resistance in freeze–thaw tests were evaluated after 56 days of curing. Additionally, the concrete pH value tests were performed. The microstructure of 2-year-old HPC specimens was analyzed using Scanning Electron Microscopy (SEM). The research proved that it is possible to obtain low-clinker High-Performance Concretes that reach compressive strength of 76–92 MPa after 28 days of curing, show high values of modulus of elasticity (49–52 GPa) as well as increased resistance to frost and water penetration under pressure.